不可溶漂浮性液态污染物向下层水体释放研究

Study on the Release of Insoluble Floating Liquid Pollutants to the Subjacent Waterbody

  • 摘要: 漂浮于水面的不可溶液态污染物的物理性质是影响其向下层水体释放强度的重要因素。根据有机污染物物理性质及相关参数的分布范围,筛选出8种代表性不可溶漂浮性液态污染物,按不同比例配制32种混合样品,共计40种样品。其中39种典型研究样品的密度、运动黏度、表面张力范围分别为0.621~0.995 g/cm3、1.81×10−6~1.00×105 mm2/s、0.024~36.200 mN/m。在39种典型样品中选择34种进行实验室动水环境物理试验,分别研究了污染物密度、运动黏度、表面张力对释放强度的影响。采用偏相关分析方法识别了影响释放强度的关键物理因素,结果表明密度、运动黏度是影响释放强度的决定性因素,表面张力对释放强度无显著影响。采用回归分析方法构建释放强度与密度、运动黏度间的多元非线性回归模型(R2=0.987)。用39种典型样品中余下5种样品独立试验数据对模型进行的验证表明平均相对误差为14.9%。

     

    Abstract: The physical properties of insoluble liquid pollutants floating on water surface are important factors affecting the release intensity to subjacent waterbody. According to the physical properties and the range of related parameters of organic pollutants, 8 representative insoluble floating liquid pollutants were selected, and 32 mixed samples were prepared with them in different proportions. The density, kinematic viscosity, and surface tension of 39 typical samples are ranged from 0.621 to 0.995 g/cm3, 1.81×10−6 to 1.00×105 mm2/s and 0.024 to 36.200 mN/m, respectively. The effects of pollutant density, kinematic viscosity, and surface tension on release intensity of the 34 samples from the 39 typical samples are studied through laboratory flowing water physical experiments, and the key physical factors affecting the release intensity were identified by partial correlation analysis. The results showed that the decisive factors affecting the release intensity are density and kinematic viscosity, while the surface tension has no significant effect on release intensity. The multivariate nonlinear regression model between release intensity, density and kinematic viscosity was established with regression analysis (R2=0.987). The model was verified through experiments with remaining 5 independent experimental data from the 39 typical samples, and the average relative error is 14.9%.

     

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