山东半岛近岸沉积物化学风化强度对古气候和海平面变化的响应机制

Chemical Weathering Intensity of Coastal Sediments off the Shandong Peninsula in Response to Climatic and Sea-level Changes

  • 摘要: 边缘海沉积物的化学风化过程与全球变化息息相关,但是其化学风化强度对古气候和海平面变化的响应机制还存在争议。本研究利用山东半岛近岸泥质区LHSD-1钻孔,通过多种化学风化指标(CIA、WIP、CIX、αAlE)恢复末次盛冰期以来沉积物的化学风化强度。分析Al/Si比值校正粒度效应发现,LHSD-1钻孔沉积物的化学风化指标受沉积物源影响较小,但在11.4~9.0 ka显著受到海平面变化导致的沉积旋回作用影响,表现为CIA(Chemical Index of Alteration)和WIP(Weathering Index of Parker)的不一致性。在高海平面时期(7.6 ka至今),CIA主要受东亚季风的控制,特别是8.2 ka、7.2 ka和4.2 ka冷事件东亚冬季风增强时,CIA快速降低,说明源区化学风化强度能快速响应气候变化。在低海平面时期,CIA等风化指标显示该时期沉积物化学强度增强,这与前人在赤道陆架研究的结论一致。我们认为,末次冰期海平面降低导致的陆架暴露是化学风化增强的主要因素,因此,我们提出在冰期-间冰期旋回尺度上,海平面变化通过控制沉积物的滞留时间来影响到边缘海沉积物的风化指标记录。这一新发现对认识冰期-间冰期旋回尺度上的全球气候变化和碳循环具有重要意义。

     

    Abstract: The chemical weathering processes of sediments in marginal seas are closely linked to global changes, yet there remains controversy regarding how their chemical weathering intensity responds to climatic and sea-level changes. Using various chemical weathering proxies (CIA, WIP, CIX, αAlE), this study utilized the sediments of core LHSD-1 from the mud area off the Shandong Peninsula to reconstruct the chemical weathering intensity since the Last Glacial Maximum. Firstly, we corrected the influence of grain-size effects using the Al/Si ratio and found that the chemical weathering proxies in the LHSD-1 core sediments were minimally affected by provenance lithology. However, between 11.4-9.0 ka, there was a notable impact of sedimentary recycles on chemical weathering caused by the deglacial sea-level change, which was reflected by the inconsistency between CIA and WIP values. During sea-level highstand (from 7.6 ka to the present), CIA values was predominantly influenced by the East Asian monsoon, particularly during the 8.2 ka, 7.2 ka, and 4.2 ka cold events when the East Asian winter monsoons were strengthened. CIA values exhibited rapid declines, indicating the quick response of chemical weathering intensity to climatic changes in the source region. Conversely, during sea-level lowstand, weathering proxies such as CIA indicated an enhancement in chemical weathering intensity, consistent with previous research findings in equatorial continental shelves. We propose that the exposure of continental shelves caused by the lower sea level during the Last Glacial Maximum is the primary factor for enhancing chemical weathering. Consequently, we suggest that sea-level changes on glacial-interglacial timescales can influence the records of weathering proxies in marginal sediments by controlling sediment residence time. These findings hold significant implications for understanding global climatic changes and carbon cycling on glacial-interglacial timescales.

     

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