海南临高海域表层沉积物重金属元素分布特征及风险评价

Distribution Characteristics and Risk Assessment of Heavy Metal Elements in Surface Sediment of Lingao Sea Area

  • 摘要: 2023年在海南临高海域采集了30个表层沉积物样品,对沉积物中的重金属元素的质量比进行分析,研究其污染状况、风险水平和污染来源。结果表明:Hg、Cr、Cu、Zn、Cd和Pb六种重金属元素质量比的分布特征相似,其高值区均为临高海域西北部、红牌港附近海域、黄龙港附近海域和文澜河,As的高值区在临高海域的中部。7种重金属的平均质量比均符合第一类海洋沉积物质量标准,所有站位中Hg、As、Cr、Cu、Zn、Cd和Pb的一类标准达标率分别为100%、87%、90%、97%、100%、100%和100%。地质累积指数结果显示7种重金属元素的污染程度依次为:As>Pb>Hg>Cr>Cd>Cu>Zn,潜在生态风险水平排序为:Hg>Cd>As>Pb>Cu>Cr>Zn,研究区域内重金属元素整体上表现为无污染和低风险。临高海域表层沉积物中的Hg、Cr、Cu、Zn、Cd和Pb主要来源于工业和海洋交通运输业;近岸的As来源于沿岸的养殖业和农业,远岸的As或与自然地质背景因素、外海输入有关。

     

    Abstract: In 2023, 30 surface sediment samples were collected from the sea area of Lingao County, Hainan, and the heavy metal contents in the sediments were analyzed to study the pollution status, risk level and sources of pollution. The results showed that the distribution characteristics of heavy metal contents of Hg, Cr, Cu, Zn, Cd and Pb were similar, and the high value areas were in the northwestern part of Lingao sea area, the sea area near Hongpai Harbour, Huanglong Harbour and Wenlan River, and the high value area of As was in the middle part of Lingao sea area. The average concentrations of all seven heavy metals, namely Hg, As, Cr, Cu, Zn, Cd, and Pb, comply with the Class I quality standards for marine sediments. Specifically, the compliance rates with Class I standards across all stations for Hg, As, Cr, Cu, Zn, Cd, and Pb are 100%, 87%, 90%, 97%, 100%, 100%, and 100%, respectively. The geological accumulation index results indicate that the pollution levels of the seven heavy metals are in the following order, As>Pb>Hg>Cr>Cd>Cu>Zn, and the potential ecological risk levels are ranked as Hg>Cd>As>Pb>Cu>Cr>Zn. Overall, the heavy metals in the study area show no pollution and low risk. The Hg, Cr, Cu, Zn, Cd, and Pb in the surface sediments of the Lingao sea mainly originate from industries and marine transportation. The As in the nearshore areas is sourced from coastal farming and agriculture, while the As in the offshore areas may be related to natural geological background factors and inputs from the open sea.

     

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